Hurkacz will face Djokovic in the Thursday opener before Jannik Sinner faces Rune in the final showdown of the day.
Djokovic has enjoyed a stunning season with three majors to his name and a points total just shy of 10,000, despite missing five ATP 1000 tournaments.
Carlos Alcaraz is the only other major champion in 2023 after toppling Djokovic at Wimbledon, but he has stumbled in recent weeks with early exits from a handful of tournaments.
They are the front-runners in this event, though it has proven to be a notoriously tricky competition to win, with six different champions in the last seven editions.
RadioTimes.com brings you the ATP Finals 2023 order of play for today.
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ATP Finals order of play today
All UK time. Times approximate, subject to change.
Thursday 16th November
Day – from 11am
Match 1 – [1] Dodig/Krajicek v [4] Gonzalez/Roger-Vasselin
Match 2 – [1] Novak Djokovic v [9] Hubert Hurkacz
Night – from 5:30pm
Match 3 – [5] Granollers/Zeballos v [7] Molteni/Gonzalez
Match 4 – [4] Jannik Sinner v [8] Holger Rune
Friday 17th November
Day – from 11am
Match 1 – [2] Skupski/Koolhof v [3] Ebden/Bopanna
Match 2 – [2] Carlos Alcaraz v [3] Daniil Medvedev
Night – from 5:30pm
Match 3 – [8] Hijikata/Kubler v [6] Ram/Salisbury
Match 4 – [5] Andrey Rublev v [7] Alexander Zverev
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Saturday 18th November
Day – from 11am
Match 1 – Doubles
Match 2 – Singles
Night – from 5:30pm
Match 3 – Doubles
Match 4 – Singles
Sunday 19th November
Day – from 3pm
Match 1 – Doubles
Match 2 – Singles
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